Citation
Zaini, Muhammad Safwan
(2024)
Physicochemical and optical properties of carbon quantum dots synthesized from watermelon peels for photovoltaic application.
Doctoral thesis, Universiti Putra Malaysia.
Abstract
The characteristics of carbon quantum dots (CQDs) are significantly influenced
by various factors such as preparation method, carbon source, doping and
others. Therefore, a comprehensive investigation into the optimal properties
of CQDs is crucial for their targeted application. In this study, CQDs were
synthesized from watermelon peels using a carbonization method. A thorough
examination of their properties was conducted, considering key parameters
such as the type of solvents used, carbon concentration, and pH values with
consideration for their application in dye-sensitized solar cells (DSSC). The
solvatochromic effect was observed, manifesting as variations in the
photoluminescence (PL) spectra when CQDs were prepared in different
solvents. PL measurements conducted at different excitation wavelengths,
revealed that the emissions of CQDs were distinctly influenced by the polarity
of the solvents. Dynamic light scattering (DLS) analysis confirmed that the size
of CQDs ranged approximately from 5.80± 0.4 to 9.74± 0.5 nm, a correlation
validated by high-resolution transmission electron microscope (HRTEM)
results. In the study on carbon concentration, the findings demonstrate a
pronounced impact on the stability of CQDs particles. Zeta potential findings
indicated that the stability of CQD particles peaked at low carbon
concentration, with zeta potential values of -62.4 mV and -64.3 mV for CQDs
dispersed in ultrapure water and methanol, respectively. Additionally,
fluorescence intensity increased parallel with carbon concentrations, and the
study identified that CQDs synthesized at 0.05-0.07 g/ml concentrations
exhibited superior stability in colloidal form. In exploring different pH
conditions, consistent pH-independent PL peak emissions were observed, yet
the intensities displayed a pH-dependent trend, amplifying from acidic to
neutral and diminishing from neutral to alkaline conditions. Moreover, in
addressing drying concerns, the study revealed the occurrence of the coffeering
effect at pH 2.5, while uniform deposition was achieved at pH 7.5. This
phenomenon was discussed based on Derjaguin, Landau, Verwey, Overbeek
(DVLO) theory. For the application of CQDs in DSSCs, CQDs in methanol
demonstrated the highest efficiency of 1.23%, surpassing CQDs in ultrapure
water (0.038%) and the control sample N719 dye (0.34%).
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Additional Metadata
Item Type: |
Thesis
(Doctoral)
|
Subject: |
Carbon dots (Nanoparticles) |
Subject: |
Dye-sensitized solar cells |
Subject: |
Photoluminescence spectroscopy |
Call Number: |
FS 2024 9 |
Chairman Supervisor: |
Mazliana Binti Ahmad Kamarudin, PhD |
Divisions: |
Faculty of Science |
Keywords: |
Carbon quantum dots, photoluminescence, photovoltaic, zeta
potential |
Depositing User: |
Ms. Rohana Alias
|
Date Deposited: |
02 Sep 2025 06:53 |
Last Modified: |
02 Sep 2025 06:53 |
URI: |
http://psasir.upm.edu.my/id/eprint/119202 |
Statistic Details: |
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