Citation
Mohamad, Nur Aqilah
(2020)
Dielectric performances of palm oil and coconut oil-based nanofluids with surfactants.
Doctoral thesis, Universiti Putra Malaysia.
Abstract
With the current interest of green technology application in transformers, PO
and CO have been introduced as viable alternatives for MO. Previous studies
have shown that the dielectric performances of these oils are comparable with
MO. These properties however could be further improved through introduction
of conductive, semi-conductive and insulative nanoparticles. Currently, there
are only few studies that have been conducted in this area for these oils, which
prompt for in-depth investigation. In addition, the roles of ionic and non-ionic
surfactants for vegetable based nanofluids are quite limited which warrants for
further investigation for its feasibility to enhance the effectiveness of the
nanoparticles.
This study aims to examine the dielectric performances of RBDPO and CO in
the presence of Fe3O4, CuO and Al2O3 nanoparticles with surfactant. The types
of surfactants used in this study were CTAB, SDS and OA. Fourier transform
infrared and particle size distribution were used to characterize the
nanoparticles in the oils. MO was also examined for comparison purpose. The
AC breakdown voltage was carried out and the data was analysed for the AC
withstand voltage at 1% probability. The Al2O3 was chosen for the lightning
breakdown voltages and PD since it could provide the highest improvement of
AC breakdown voltage. The lightning breakdown test was carried out based on
needle-sphere electrodes configuration at the gap distance of 25 mm under
positive and negative polarities. The PD were measured based on needlesphere
electrode configuration at the gap distance of 50 mm. Rising voltage
method was applied for the lightning breakdown voltage and PDIV
measurements. A photo multiplier tube was also used to detect faint optical
signals from weakly emitting sources during the PD test.
It is found that only Al2O3 can improve the average AC breakdown voltage of
RBDPO and CO. The AC withstand voltages at 1% probability for RBDPO, CO
and MO could be improved through introduction of Fe3O4, CuO and Al2O3 at
certain volume concentrations. OA could provide the highest improvement of
the AC withstand voltages at 1% probability for RBDPO, CO and MO based
Al2O3 nanofluids. Al2O3 could improve both positive and negative lightning
breakdown voltages of RBDPO and CO. Under both polarities, CTAB provide
the highest improvements on the lightning breakdown voltages of RBDPO, CO
and MO based Al2O3 nanofluids. CTAB further increases the times to
breakdown and decrease the average streamer velocities of RBDPO based
Al2O3 nanofluid under both polarities. The same finding is observed for CO
under positive polarity with CTAB and SDS as well as under negative polarity
with all surfactants. It is found that, RBDPO, CO and MO based Al2O3
nanofluids have second mode of streamer whereby the streamer velocities are
from 1 km/s to 3.4 km/s regardless with or without surfactants. The presence of
Al2O3 does improve the PDIV of RBDPO and CO without and with either CTAB
or SDS. The maximum PD amplitudes of RBDPO, CO and MO could further be
enhanced in the presence of Al2O3 with either SDS or OA. On the other hands,
the PD repetition rates for RBDPO, CO and MO improve in the presence of
Al2O3 regardless with and without surfactants. Al2O3 leads to the increment of
light signal emissions for RBDPO and CO and it is further enhanced in the
presence of surfactants.
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