Citation
How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim
(2007)
Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate.
Acta Crystallographica Section E: Structure Reports Online, 63 (3).
pp. 3023-3024.
ISSN 1600-5368
Abstract
The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring and the dithiocarbazate unit is 103.70 (1). The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1).There are strong – stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5)and 3.28 (5) A ° , respectively]. A long-distance intermolecular N—H N hydrogen bond [3.171 (2) A ° ] also stabilizes the structure.
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Official URL or Download Paper: http://dx.doi.org/10.1107/S1600536807025056
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1107/S1600536807025056 |
| Publisher: | International Union of Crystallography |
| Depositing User: | Najwani Amir Sariffudin |
| Date Deposited: | 20 Jul 2010 06:28 |
| Last Modified: | 27 May 2013 07:35 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536807025056 |
| URI: | http://psasir.upm.edu.my/id/eprint/7515 |
| Statistic Details: | View Download Statistic |
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