Citation
Muhd Noor, Noor Dina and Matsuura, Hiroaki and Nishikawa, Koji and Tai, Hulin and Hirota, Shun and Kim, Jaehyun and Kang, Jiyoung and Tateno, Masaru and Yoon, Ki-Seok and Ogo, Seiji and Kubota, Shintaro and Shomura, Yasuhito and Higuchi, Yoshiki
(2018)
Redox-dependent conformational changes of a proximal [4Fe-4S] cluster in Hyb-type [NiFe]-hydrogenase to protect the active site from O2.
Chemical Communications, 54 (87).
12385 - 12388.
ISSN 1359-7345; ESSN: 1364-548X
Abstract
Citrobacter sp. S-77 [NiFe]-hydrogenase harbors a standard [4Fe–4S] cluster proximal to the Ni–Fe active site. The presence of relocatable water molecules and a flexible aspartate enables the [4Fe–4S] to display redox-dependent conformational changes. These structural features are proposed to be the key aspects that protect the active site from O2 attack.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Biotechnology and Biomolecular Sciences |
| DOI Number: | https://doi.org/10.1039/C8CC06261G |
| Publisher: | Royal Society of Chemistry |
| Keywords: | Redox-dependent; Proximal [4Fe-4S] cluster; Hyb-type [NiFe]-hydrogenase; O2 attack |
| Depositing User: | Ms. Nida Hidayati Ghazali |
| Date Deposited: | 02 Mar 2022 09:00 |
| Last Modified: | 02 Mar 2022 09:00 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1039/C8CC06261G |
| URI: | http://psasir.upm.edu.my/id/eprint/73727 |
| Statistic Details: | View Download Statistic |
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