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Energy levels of natural sensitizers extracted from rengas (Gluta spp.) and mengkulang (Heritiera elata) wood for dye-sensitized solar cells


Citation

Safie, Nur Ezyanie and Ahmad Ludin, Norasikin and Hamid, Norul Hisham and Sepeai, Suhaila and Mat Teridi, Mohd Asri and Ibrahim, Mohd Adib and Sopian, Kamaruzzaman and Arakawa, Hironori (2017) Energy levels of natural sensitizers extracted from rengas (Gluta spp.) and mengkulang (Heritiera elata) wood for dye-sensitized solar cells. Materials for Renewable and Sustainable Energy, 6 (2). pp. 1-9. ISSN 2194-1459; ESSN: 2194-1467

Abstract

Dye-sensitized solar cells (DSSCs) are fabricated using natural sensitizers extracted from rengas (Gluta spp.) and mengkulang (Heritieraelata) wood. The natural sensitizers are extracted using a cold extraction and the Soxhlet extraction methods. This paper presents the results of the analysis of the optical characteristics of the sensitizers via ultraviolet–visible spectrophotometry and Fourier transform infrared spectroscopy. The optical band gap and the highest occupied molecular orbital (HOMO)–lowest unoccupied molecular orbital (LUMO) levels of each investigated sensitizer are calculated on the basis of the analyzed data collected from photoluminescence and cyclic voltammetry. The DSSCs with the mengkulang sensitizer have better conversion efficiency (ŋ = 0.1695%) than the DSSCs with the rengas sensitizer (ŋ = 0.109%). The performance of the DSSCs indicates an increment as the ratios of the mixed mengkulang:rengas (60%:40%) and mengkulang:rengas (40%:60%) sensitizers increase up to 0.296 and 0.292%, respectively.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Forestry
DOI Number: https://doi.org/10.1007/s40243-017-0089-1
Publisher: SpringerOpen
Keywords: Optical band gap; HOMO–LUMO level; Natural sensitizer; DSSCs
Depositing User: Nurul Ainie Mokhtar
Date Deposited: 08 Jan 2019 08:40
Last Modified: 08 Jan 2019 08:40
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1007/s40243-017-0089-1
URI: http://psasir.upm.edu.my/id/eprint/61717
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