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New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum


Citation

Rahmani, Mawardi and Yap, Taufiq Yun Hin and Mohd Ismail, Hazar Bebe and Md. Sukari, Mohd Aspollah and Waterman, Peter G. (1994) New coumarin and dihydrocinnamic acid derivatives from two Malaysian populations of Micromelum minutum. Phytochemistry, 37 (2). pp. 561-564. ISSN 0031-9422; ESSN: 1873-3700

Abstract

Three novel compounds, two compounds and a dihydrocinnamic acid, have been isolated from two collections of Micromelum minutum and identified by means of NMR spectroscopy. A sample collected from Pahang gave the typical coumarin micromelin and a new dihydrocinnamic acid derivative of micromelin which was identified as 1,2-seco-dihydromicromelin. The second sample, collected from Kelantan, gave two new tetracyclic coumarins, microminutinin and 6-methoxymicrominutinin, which possess a fused bifurano system that appears to be derived by cyclization of a 7-oxygenated-8-(1,2-dimethyl)propylcoumarin precursor. The structure of microminutinin is revised from that proposed in a previous paper.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1016/0031-9422(94)85100-X
Publisher: Elsevier Science
Keywords: Micromelum minutum; Rutaceae; Coumarins; Microminutinin; 6-methoxymicrominutinin; Dihydrocinnamic acid; 1,2-seco-dihydromicromelin; NMR spectroscopy
Depositing User: Nabilah Mustapa
Date Deposited: 04 Jul 2017 02:48
Last Modified: 05 Aug 2024 03:00
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1016/0031-9422(94)85100-X
URI: http://psasir.upm.edu.my/id/eprint/56240
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