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Miscible transparent polymethylmethacrylate/cellulose acetate propionate blend: optical, morphological, and thermomechanical properties


Citation

Raouf, Raouf Mahmood and Abdul Wahab, Zaidan and Ibrahim, Nor Azowa and Talib, Zainal Abidin and Buong, Woei Chieng (2016) Miscible transparent polymethylmethacrylate/cellulose acetate propionate blend: optical, morphological, and thermomechanical properties. BioResources, 11 (2). 3466 - 3480. ISSN 1930-2126

Abstract

To obtain a high transmittance blend within ultraviolet and visible regions, various transparent samples of ascending percentages of polymethylmethacrylate (PMMA)/cellulose acetate propionate (CAP) were prepared by melt blending using a twin screw extruder. These blends were characterised by ultraviolet-visible spectroscopy, and the curves illustrated that the blending ratio of 10% CAP in PMMA meets the required purpose. The morphological, mechanical, and thermal properties for pure PMMA and the PMMA/CAP 10% blend were investigated using X-ray diffraction, scanning electron microscopy, dynamic mechanical analysis, and thermogravimetric analysis. The results showed that the PMMA/CAP 10% blend has an amorphous structure and low stiffness than pure PMMA. The miscible PMMA/CAP 10% blend exhibited mechanical stability below the glass transition temperature (Tg), with a slight increase in Tg value relative to that of pure PMMA. The study also demonstrated that the intermolecular interaction between blend elements has an effective influence on the physical properties of the blend.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
Institute of Advanced Technology
DOI Number: https://doi.org/10.15376/biores.11.2.3466-3480
Publisher: College of Natural Resources, North Carolina State University
Keywords: Cellulose acetate propionate; Poly (methylmethacrylate); Miscible; Ultraviolet; Blend
Depositing User: Ms. Ainur Aqidah Hamzah
Date Deposited: 18 Mar 2022 01:53
Last Modified: 18 Mar 2022 01:53
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.15376/biores.11.2.3466-3480
URI: http://psasir.upm.edu.my/id/eprint/53291
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