Citation
Israr, Hira and Rasool, Nasir and Rizwan, Komal and Hashmi, Muhammad Ali and Mahmood, Tariq and Rashid, Umer and Hussein, Mohd Zobir and Akhtar, Muhammad Nadeem
(2019)
Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses.
Symmetry, 11 (5).
art. no. 622.
pp. 1-11.
ISSN 2073-8994
Abstract
We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities.
Download File
Official URL or Download Paper: https://www.mdpi.com/2073-8994/11/5/622
|
![[img]](http://psasir.upm.edu.my/style/images/fileicons/text.png)
Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Institute of Advanced Technology |
| DOI Number: | https://doi.org/10.3390/sym11050622 |
| Publisher: | MDPI |
| Keywords: | Aniline; Suzuki coupling; Density functional theory; Reactivity; Palladium; Optical |
| Depositing User: | Nabilah Mustapa |
| Date Deposited: | 04 May 2020 16:25 |
| Last Modified: | 04 May 2020 16:25 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.3390/sym11050622 |
| URI: | http://psasir.upm.edu.my/id/eprint/38377 |
| Statistic Details: | View Download Statistic |
Actions (login required)
 |
View Item |