Citation
Tayamon, Shahedeh and Tiekink, Edward R. T. and Nikpour, Farzad and S. A. Ravoof, Thahira Begum and Mohamed Tahir, Mohamad Ibrahim and Karen, Anne Crouse
(2014)
Isolation, characterization and x-ray structure determination of 2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole.
Journal of Chemical Crystallography , 44 (1).
pp. 1-5.
ISSN 1074-1542; ESSN: 1572-8854
Abstract
The reaction of hydrazine hydrate with carbon disulfide and 4-methylbenzyl chloride in basic solution yielded 2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole (C18H18N2S3, compound 1) in addition to the expected S-4-methylbenzyldithiocarbazate. The molecule has approximate twofold symmetry with the C=S bond lying on the pseudo axis. The five membered ring is planar with the three S atoms mutually syn, and with pendent 4-methylbenzylthio substituents; the dihedral angle between the terminal rings is 52.21(7)°. The compound 1 crystallizes in the triclinic space group \(P\bar{1}\) with a = 6.0139(3) Å, b = 11.8694(7) Å, c = 12.6330(7) Å, α = 72.583(5)°, β = 82.827(4)°, γ = 89.882(4)° and Z = 2.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1007/s10870-013-0474-2 |
| Publisher: | Springer |
| Keywords: | Dithiocarbazate; 1,3,4-thiadiazole; Supramolecular structure; Crystal structure |
| Depositing User: | Nurul Ainie Mokhtar |
| Date Deposited: | 10 Dec 2015 03:37 |
| Last Modified: | 10 Dec 2015 03:37 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1007/s10870-013-0474-2 |
| URI: | http://psasir.upm.edu.my/id/eprint/34293 |
| Statistic Details: | View Download Statistic |
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