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Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)


Citation

Badri, M. and Jamieson, J. W. S. (1977) Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II). Canadian Journal of Chemistry, 55 (20). pp. 3530-3535. ISSN 0008-4042; ESSN: 1480-3291

Abstract

Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been mea- sured. For each of these ammine systems, the maximum difference in heat of solution, ex- pressed in kcal(mol of heptaammine, has been found to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaammine complex of the metal ion.


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Additional Metadata

Item Type: Article
Divisions: Universiti Pertanian Malaysia
Publisher: N R C Research Press
Keywords: Metal ion; Hexaammine complex
Depositing User: Azhar Abdul Rahman
Date Deposited: 21 Apr 2015 08:22
Last Modified: 21 Apr 2015 08:22
URI: http://psasir.upm.edu.my/id/eprint/33953
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