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Physicochemical study of 3,4-dichlorophenoxyacetic acid intercalated into hydrotalcite-like compound by ion exchanged method


Citation

Sheikh Mohd Ghazali, Sheikh Ahmad Izaddin and Sarijo, Siti Halimah and Hussein, Mohd Zobir (2016) Physicochemical study of 3,4-dichlorophenoxyacetic acid intercalated into hydrotalcite-like compound by ion exchanged method. Materials Science Forum, 846. pp. 440-447. ISSN 0255-5476; ESSN: 1662-9752

Abstract

The intercalation of herbicide, 3,4-dicholorophenoxyacetic acid (3,4D), into zinc-aluminium-layered double hydroxide (LDH) for the formation of a new nanocomposite ZADX, was accomplished via anion exchange method. Due to the intercalation of 3,4D with LDH interlayer domain, basal spacing expanded from 8.9Å in the ZAL to 17.7-19.0 Å in the ZADX. The percentage loading of 3,4D in the ZADX is 51.4 % (w/w). The FTIR spectra of the nanocomposite shows resemblance peaks of the 3,4D and Zn-Al-layered double hydroxide indicating the inclusion of 3,4D into the layered double hydroxide. Surface area of the resulting nanocomposite increased from 1.3 to 7.14 m2g-1 with the nitrogen adsorption-desorption of type IV.


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Official URL or Download Paper: http://www.scientific.net/MSF.846.440

Additional Metadata

Item Type: Article
Divisions: Institute of Advanced Technology
DOI Number: https://doi.org/10.4028/www.scientific.net/MSF.846.440
Publisher: Trans Tech Publications
Keywords: 3,4-dichlorophenoxyaceticacid; Herbicide; Hydrotalcite-like compound; Intercalation
Depositing User: Nurul Ainie Mokhtar
Date Deposited: 10 Nov 2017 04:55
Last Modified: 10 Nov 2017 04:55
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.4028/www.scientific.net/MSF.846.440
URI: http://psasir.upm.edu.my/id/eprint/29252
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