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Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.


Begum, Thahira and Omar, Siti Aminah and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne (2012) Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. Acta Crystallographica Section E: Structure Reports Online, E68 (4). pp. 390-391. ISSN 1600-5368


In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octa­hedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H(...)N hydrogen-bonding inter­actions.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536812009592
Publisher: International Union of Crystallography
Keywords: Schiff base; Transition metal complexes; Saccharin.
Depositing User: Nur Farahin Ramli
Date Deposited: 12 Jul 2013 07:29
Last Modified: 31 Oct 2013 01:50
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536812009592
URI: http://psasir.upm.edu.my/id/eprint/25231
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