Citation
Begum, Thahira and Omar, Siti Aminah and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne
(2012)
Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
Acta Crystallographica Section E: Structure Reports Online, E68 (4).
pp. 390-391.
ISSN 1600-5368
Abstract
In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H(...)N hydrogen-bonding interactions.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1107/S1600536812009592 |
| Publisher: | International Union of Crystallography |
| Keywords: | Schiff base; Transition metal complexes; Saccharin. |
| Depositing User: | Nur Farahin Ramli |
| Date Deposited: | 12 Jul 2013 07:29 |
| Last Modified: | 31 Oct 2013 01:50 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536812009592 |
| URI: | http://psasir.upm.edu.my/id/eprint/25231 |
| Statistic Details: | View Download Statistic |
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