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{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate.


Citation

Omar, Siti Aminah and Begum, Thahira and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne (2012) {S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 68 (-). pp. 316-317. ISSN 1600-5368; ESSN:1600-5368

Abstract

The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one mol­ecule in the asymmetric unit, along with a solvent water mol­ecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octa­hedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H(...)N and O—H(...)S hydrogen bonding between the solvent water mol­ecule and the uncoordinated N and S atoms of neighbouring ligands.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536812006952
Publisher: International Union of Crystallography
Keywords: X-ray crystallographic analysis, Ni(II) complex.
Depositing User: Nur Farahin Ramli
Date Deposited: 02 Aug 2013 04:07
Last Modified: 02 Aug 2013 04:07
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536812006952
URI: http://psasir.upm.edu.my/id/eprint/25020
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