Citation
Omar, Siti Aminah and Begum, Thahira and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne
(2012)
{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate.
Acta Crystallographica Section E: Structure Reports Online, 68 (-).
pp. 316-317.
ISSN 1600-5368; ESSN:1600-5368
Abstract
The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H(...)N and O—H(...)S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1107/S1600536812006952 |
| Publisher: | International Union of Crystallography |
| Keywords: | X-ray crystallographic analysis, Ni(II) complex. |
| Depositing User: | Nur Farahin Ramli |
| Date Deposited: | 02 Aug 2013 04:07 |
| Last Modified: | 02 Aug 2013 04:07 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536812006952 |
| URI: | http://psasir.upm.edu.my/id/eprint/25020 |
| Statistic Details: | View Download Statistic |
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