S-Quinolin-2-ylmethyldithiocarbazate.

Citation

How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) S-Quinolin-2-ylmethyldithiocarbazate. Acta Crystallographica Section E: Structure Reports Online, 63 (7). pp. 3137-3138. ISSN 1600-5368

Abstract

In the title compound, C11H11N2S2, there is an intramolecular N-H...N [2.778 (2) Å] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1)° with the dithiocarbazate group. Bond angles for both S-C-S [115.66 (8)°] and N-C-S [119.05 (11)°] are comparable with cis-trans S-methyldithiocarbazate but differ from those found in trans-cis S-methyldithiocarbazate and trans-cis S-benzyldithiocarbazate. This is due to the N-H...N hydrogen bond that exists only in the cis-trans conformation found for the title compound.

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Additional Metadata

Item Type:	Article
Divisions:	Faculty of Science
DOI Number:	https://doi.org/10.1107/S1600536807024609
Publisher:	International Union of Crystallography
Keywords:	Dithiocarbazate; Crystal analysis.
Depositing User:	Nur Farahin Ramli
Date Deposited:	28 Feb 2014 07:00
Last Modified:	17 Sep 2015 03:30
Altmetrics:	http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536807024609
URI:	http://psasir.upm.edu.my/id/eprint/24956
Statistic Details:	View Download Statistic

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