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Influence of organic species on the characteristics of Mo-V oxide


Citation

Woi, Pei Meng and Ramli, Irmawati and Yap, Taufiq Yun Hin (2007) Influence of organic species on the characteristics of Mo-V oxide. The Malaysian Journal of Analytical Sciences, 11 (1). pp. 160-165. ISSN 1394-2506

Abstract

This study investigates on the effect of organic species on the characteristics of molybdenum-vanadium mixed oxide catalysts. The MoV precursors were prepared by homogeneous precipitation method using urea hydrolysis. The oxides were later treated with three organic species namely polyvinyl alcohol (PVA), malic acid (MA) and adipic acid (AA). The solutions were refluxed in a prescribed time. The solid obtained were calcined and subsequently denoted as MoV(PVA), MoV(MA) and MoV(AA). Interesting results in which high surface area values (SBET) were obtained in the range between 10 to 20 m2 g-1. XRD reckoned the samples are in highly crystalline form. H2-Temperature programmed reduction analysis showed that the total number of oxygen removed are 1.4 x 1022 atoms g-1, 3.3 x 1022 atoms g-1 and 1.8 x 1022 atoms g-1 for MoV(PVA), MoV(MA) and MoV(AA) respectively.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
Publisher: Malaysian Analytical Sciences Society
Keywords: Mo-V oxides; Homogeneous precipitation; Organic species; H2-TPR
Depositing User: Najwani Amir Sariffudin
Date Deposited: 30 Nov 2011 08:04
Last Modified: 23 Nov 2016 09:19
URI: http://psasir.upm.edu.my/id/eprint/11936
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