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Unlocking the potential of magnetic biochar in wastewater purification: a review on the removal of bisphenol a from aqueous solution


Citation

Katibi, Kamil Kayode and Shitu, Ibrahim Garba and Md. Yunos, Khairul Faezah and Azis, Rabaah Syahidah and Iwar, Raphael Terungwa and Adamu, Suleiman Bashir and Umar, Abba Mohammed and Adebayo, Kehinde Raheef (2024) Unlocking the potential of magnetic biochar in wastewater purification: a review on the removal of bisphenol a from aqueous solution. Environmental Monitoring and Assessment, 196 (5). art. no. 492. pp. 1-38. ISSN 0167-6369; eISSN: 1573-2959

Abstract

Bisphenol A (BPA) is an essential and extensively utilized chemical compound with significant environmental and public health risks. This review critically assesses the current water purification techniques for BPA removal, emphasizing the efficacy of adsorption technology. Within this context, we probe into the synthesis of magnetic biochar (MBC) using co-precipitation, hydrothermal carbonization, mechanical ball milling, and impregnation pyrolysis as widely applied techniques. Our analysis scrutinizes the strengths and drawbacks of these techniques, with pyrolytic temperature emerging as a critical variable influencing the physicochemical properties and performance of MBC. We explored various modification techniques including oxidation, acid and alkaline modifications, element doping, surface functional modification, nanomaterial loading, and biological alteration, to overcome the drawbacks of pristine MBC, which typically exhibits reduced adsorption performance due to its magnetic medium. These modifications enhance the physicochemical properties of MBC, enabling it to efficiently adsorb contaminants from water. MBC is efficient in the removal of BPA from water. Magnetite and maghemite iron oxides are commonly used in MBC production, with MBC demonstrating effective BPA removal fitting well with Freundlich and Langmuir models. Notably, the pseudo-second-order model accurately describes BPA removal kinetics. Key adsorption mechanisms include pore filling, electrostatic attraction, hydrophobic interactions, hydrogen bonding, π-π interactions, and electron transfer surface interactions. This review provides valuable insights into BPA removal from water using MBC and suggests future research directions for real-world water purification applications.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Engineering
Faculty of Science
Institute of Advanced Technology
DOI Number: https://doi.org/10.1007/s10661-024-12574-6
Publisher: Springer Science and Business Media Deutschland GmbH
Keywords: Adsorption; Bisphenol A; Co-precipitation; Magnetic biochar; Removal mechanism
Depositing User: Ms. Zaimah Saiful Yazan
Date Deposited: 11 Sep 2025 07:45
Last Modified: 11 Sep 2025 07:45
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1007/s10661-024-12574-6
URI: http://psasir.upm.edu.my/id/eprint/119086
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