UPM Institutional Repository

Optimising bismuth magnesium niobate pyrochlores as potential ceramic dielectrics: Reaction progression, phase equilibria and impedance properties


Citation

Tan, Kar Ban and Tan, P.Y. and Feng, Y. and Khaw, C.C. and Lim, T.Z. Alvin and Kechik, M.M.A. and Chen, S.K. and Chan, K.Y. and Lu, M. and Sun, J. and Zhou, D. (2025) Optimising bismuth magnesium niobate pyrochlores as potential ceramic dielectrics: Reaction progression, phase equilibria and impedance properties. Ceramics International. pp. 1-15. ISSN 0272-8842;

Abstract

The phase-pure Bi2O3-MgO-M2O5 (BMN) cubic pyrochlores formed across a broad compositional range, with bismuth content varying from 41.88 to 44.50 mol %. The quadrilateral subsolidus region is defined by two substitution mechanisms: (i) Mg2+ substitution by Nb5+, balanced by oxygen stoichiometry variations and (ii) one-to-one Bi3+ replacement by Nb5+, with charge compensation by O2− . This yields a general formula of Bi3.36+xMg1.92-yNb2.72-x + yO13.76-x+(3/2)y, involving two variables with the corresponding subsolidus solution limits of 0.10 ≤ x ≤ 0.20 and 0.00 ≤ y ≤ 0.16, respectively. Notably, these BMN pyrochlores exhibit high dielectric constants, ε′ in the range of 167–204 at 30 ◦C, 1 MHz and low dielectric losses, tan δ in the order of 10− 4 - 10− 3 . The elevated dielectric constant is likely due to the enhanced polarisability of Nb2O5 within the crucial BO6 octahedra of the pyrochlore structure. Furthermore, these pyrochlores display negative temperature coefficients of permittivity, TCε’ ranging from − 528 to − 742 ppm/◦C at 30–300 ◦C and 1 MHz. These thermally stable and highly insulating BMN pyrochlores with high activation energies, Ea >1.0 eV, are promising candidate for potential application in ceramic capacitors.


Download File

[img] Text
117145.pdf - Published Version
Restricted to Repository staff only

Download (11MB)

Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1016/j.ceramint.2025.03.122
Publisher: Elsevier
Keywords: Impedance; Niobate; Phase equilibria; Pyrochlores
Depositing User: Scopus
Date Deposited: 05 May 2025 08:22
Last Modified: 05 May 2025 08:22
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1016/j.ceramint.2025.03.122
URI: http://psasir.upm.edu.my/id/eprint/117145
Statistic Details: View Download Statistic

Actions (login required)

View Item View Item