Citation
Chnoong, Kheng Lee and Goik, See Lim and West, Anthony R.
(1994)
Phase diagrams and stoichiometries of the solid electrolytes, Bi 4V2O11: M, M = Co, Cu, Zn, Ca, Sr.
Journal of Materials Chemistry, 4 (9).
pp. 1441-1444.
ISSN 0959-9428; eISSN: 0959-9428
Abstract
The compositional ranges of Bi4V2O11 solid solutions containing Co, Cu, Zn, Ca and Sr have been determined by means of a phase diagram study at solidus temperatures. Depending on the size of the divalent cation, at least three and probably four mechanisms for accommodating variable cation content have been identified. These are: V ⇌ Bi, V ⇌ M, Bi ⇌ M and probably, formation of interstitial M. Most previous studies have focused on the single mechanism V ⇌ M whereas, in fact, the solid solutions are shown to be far more varied and extensive than previously supposed.
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Additional Metadata
Item Type: | Article |
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Divisions: | Universiti Pertanian Malaysia |
DOI Number: | https://doi.org/10.1039/jm9940401441 |
Publisher: | Royal Society of Chemistry |
Keywords: | Bi4V2o11; Solid electrolytes; Phase diagrams; Stoichiometry; Solid solutions; Co; Cu; Zn; Ca; Sr; Divalent cations |
Depositing User: | Ms. Zaimah Saiful Yazan |
Date Deposited: | 08 Jul 2025 04:13 |
Last Modified: | 08 Jul 2025 04:13 |
Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1039/jm9940401441 |
URI: | http://psasir.upm.edu.my/id/eprint/115596 |
Statistic Details: | View Download Statistic |
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