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Synthesis and structural characterization of some adducts of 1,4-dithian and -oxathian with silver(I) nitrate and perchlorate


Citation

Effendy and Silong, Sidik and Skelton, Brian W. and White, Allan H. (2003) Synthesis and structural characterization of some adducts of 1,4-dithian and -oxathian with silver(I) nitrate and perchlorate. Australian Journal of Chemistry, 56 (1). pp. 23-36. ISSN 0004-9425

Abstract

The crystallographic structures of 1,4-oxathian (O(CH2CH2)2S) and its 1:1 silver(I) nitrate adduct were redetermined The 1:1 and 1.5:1 adducts of 1,4-dithian (S(CH2CH2)2S) with silver(I) nitrate and perchlorate, respectively, were also determined. The nitrate complexes formed two-dimensional polymers while the perchlorate formed a three-dimensional polymer (see Figure). The Ag coordination environments were unique in each complex formed.


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Official URL or Download Paper: https://www.publish.csiro.au/ch/CH02129

Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1071/CH02129
Publisher: CSIRO Publishing
Keywords: Crystal structure; X-ray crystallography; Coordination complexes
Depositing User: Ms. Nuraida Ibrahim
Date Deposited: 03 Mar 2025 07:54
Last Modified: 03 Mar 2025 07:54
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1071/CH02129
URI: http://psasir.upm.edu.my/id/eprint/115356
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