Citation
Lajis, Nordin Hj. and Khan, Mohammad Niyaz
(1992)
Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
Tetrahedron, 48 (6).
pp. 1109-1114.
ISSN 0040-4020; eISSN: 0040-4020
Abstract
The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science Universiti Pertanian Malaysia |
| DOI Number: | https://doi.org/10.1016/s0040-4020(01)88206-5 |
| Publisher: | Elsevier |
| Keywords: | Stereoselective coupling; Solvolytic; p-Methoxyphenylmagnesium bromide; Substituted allylic chlorides; Regioselectivity; Stereoselectivity; Intermediate formation; Solvent effects; Reaction mechanisms; Stereochemistry; Organic chemistry |
| Depositing User: | Mohamad Jefri Mohamed Fauzi |
| Date Deposited: | 03 Dec 2024 04:03 |
| Last Modified: | 03 Dec 2024 04:03 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1016/s0040-4020(01)88206-5 |
| URI: | http://psasir.upm.edu.my/id/eprint/114121 |
| Statistic Details: | View Download Statistic |
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