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Recent advances in catalytic and non-catalytic epoxidation of terpenes: a pathway to bio-based polymers from waste biomass


Citation

Gunam Resul, Mohamad Faiz Mukhtar and Abdul Rehman, . and Saleem, Faisal and Usman, Muhammd and Lopez Fernandez, Ana María and Eze, Valentine C. and Harvey, Adam P. (2023) Recent advances in catalytic and non-catalytic epoxidation of terpenes: a pathway to bio-based polymers from waste biomass. RSC Advances, 13 (47). 32940 - 32971. ISSN 2046-2069

Abstract

Epoxides derived from waste biomass are a promising avenue for the production of bio-based polymers, including polyamides, polyesters, polyurethanes, and polycarbonates. This review article explores recent efforts to develop both catalytic and non-catalytic processes for the epoxidation of terpene, employing a variety of oxidizing agents and techniques for process intensification. Experimental investigations into the epoxidation of limonene have shown that these methods can be extended to other terpenes. To optimize the epoxidation of bio-based terpene, there is a need to develop continuous processes that address limitations in mass and heat transfer. This review discusses flow chemistry and innovative reactor designs as part of a multi-scale approach aimed at industrial transformation. These methods facilitate continuous processing, improve mixing, and either eliminate or reduce the need for solvents by enhancing heat transfer capabilities. Overall, the objective of this review is to contribute to the development of commercially viable processes for producing bio-based epoxides from waste biomass.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Engineering
DOI Number: https://doi.org/10.1039/D3RA04870E
Publisher: Royal Society of Chemistry
Keywords: Bio-based; Bio-based polymers; Catalytic epoxidation; Catalytic process; Continuous process; Experimental investigations; Non-catalytic; Oxidizing agents; Process intensification; Waste biomass; Climate action; Industry; Innovation and infrastructure
Depositing User: Ms. Che Wa Zakaria
Date Deposited: 26 Sep 2024 07:55
Last Modified: 26 Sep 2024 07:55
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1039/D3RA04870E
URI: http://psasir.upm.edu.my/id/eprint/108688
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