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Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate


How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 63 (3). pp. 3023-3024. ISSN 1600-5368

Abstract / Synopsis

The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring and the dithiocarbazate unit is 103.70 (1). The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1).There are strong – stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5)and 3.28 (5) A ° , respectively]. A long-distance intermolecular N—H N hydrogen bond [3.171 (2) A ° ] also stabilizes the structure.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: 10.1107/S1600536807025056
Publisher: International Union of Crystallography
Depositing User: Najwani Amir Sariffudin
Date Deposited: 20 Jul 2010 14:28
Last Modified: 27 May 2013 15:35
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