Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate

How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate. Acta Crystallographica Section e, 63 (3). pp. 3023-3024. ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536807025056

Abstract

The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring and the dithiocarbazate unit is 103.70 (1). The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1).There are strong – stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5)and 3.28 (5) A ° , respectively]. A long-distance intermolecular N—H N hydrogen bond [3.171 (2) A ° ] also stabilizes the structure.

Item Type:Article
Faculty or Institute:Faculty of Science
Publisher:International Union of Crystallography
DOI Number:10.1107/S1600536807025056
Altmetrics:http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536807025056
ID Code:7515
Deposited By: Najwani Amir Sariffudin
Deposited On:20 Jul 2010 06:28
Last Modified:27 May 2013 07:35

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