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Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate

How, Fiona Ni Foong["lib/metafield:join_name" not defined]Watkin, David J.["lib/metafield:join_name" not defined]Crouse, Karen Anne["lib/metafield:join_name" not defined]Mohamed Tahir, Mohamed Ibrahim (2007) Benzyl N0-[1-(3-pyridyl)ethylidene]-hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 63 (3). ["lib/metafield/pagerange:range" not defined

]. ISSN 1600-5368

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The title compound, C15H5N2S2, crystallizes as a trans–cis conformer. The thione sulfur is in a trans position with the methyl pyridyl fragment with respect to the C—N bond but adopts a cis position with the benzyl ring across the C—S bond. The dihedral angle between the planar quinoline ring and the dithiocarbazate unit is 103.70 (1). The inclination of the dithiocarbazate unit with the benzyl group is 17.20 (1).There are strong – stacking interactions between pairs of dithiocarbazate units and also pairs of pyridine rings [3.27 (5)and 3.28 (5) A ° , respectively]. A long-distance intermolecular N—H N hydrogen bond [3.171 (2) A ° ] also stabilizes the structure.

["eprint_fieldname_type" not defined]:Article
Faculty or Institute:Faculty of Science
Publisher:International Union of Crystallography
DOI Number:10.1107/S1600536807025056
ID Code:7515
Deposited By: Najwani Amir Sariffudin
Deposited On:20 ["lib/utils:month_short_07" not defined] 2010 06:28
["eprint_fieldname_lastmod" not defined]:27 ["lib/utils:month_short_05" not defined] 2013 07:35

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