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Reaction parameters for the synthesis of N,N-dimethyl fatty hydrazides from oil


Citation

Ahmad, Norashikin and Aldrin, Zafarizal and Hassan, Hazimah and Ahmad @ Ayob, Mansor and Wan Yunus, Wan Md Zin (2015) Reaction parameters for the synthesis of N,N-dimethyl fatty hydrazides from oil. Journal of Oleo Science, 64 (1). pp. 41-49. ISSN 1345-8957; ESSN: 1347-3352

Abstract

Hydrazide derivatives have been synthesized from methyl esters, hydrazones and vegetable oils. They are important due to their diverse applications in pharmaceutical products, detergents as well as in oil and gas industries. The chemical synthesis of fatty hydrazides is well-established; however, only a few publications described the synthesis of fatty hydrazide derivatives, particularly, when produced from refined, bleached and deodorized palm olein. Here, the synthesis and characterization of N,N-dimethyl fatty hydrazides are reported. The N,N-dimethyl fatty hydrazides was successfully synthesized from fatty hydrazides and dimethyl sulfate in the presence of potassium hydroxide with the molar ratio of 1:1:1, 6 hours reaction time and 80℃ reaction temperature in ethanol. The product yield and purity were 22% and 89%, respectively. The fatty hydrazides used were synthesized from refined, bleached and deodorized palm olein with hydrazine monohydrate at pH 12 by enzymatic route. Fourier transform infrared, gas chromatography and nuclear magnetic resonance (NMR) spectroscopy techniques were used to determine the chemical composition of N,N-dimethyl fatty hydrazides. Proton NMR confirmed the product obtained were N,N-dimethyl fatty hydrazides.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.5650/jos.ess14097
Publisher: Japan Oil Chemists' Society
Keywords: Fatty hydrazides; N,N-dimethyl fatty hydrazides; Dimethyl sulfate; Potassium hydroxide
Depositing User: Ms. Nida Hidayati Ghazali
Date Deposited: 23 Mar 2022 06:21
Last Modified: 23 Mar 2022 06:21
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.5650/jos.ess14097
URI: http://psasir.upm.edu.my/id/eprint/46085
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