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Rare earths complexes of single arm N-aryl Schiff base ligand


Abid, Khalil Khalaf and Al-Barody, Sadeem Mohammad and Ahmad, Haslina (2014) Rare earths complexes of single arm N-aryl Schiff base ligand. Journal of Applied Chemistry, 2 (1). pp. 71-81. ISSN 2348-0408


A synthesized ligand N – ( 2 – hydroxyphenyl) – 4 – n – butylsalicylaldimine (H2L) was used to prepare a series of mononuclear lanthanide complexes of the type [LnH2L(HL)2Cl] (Ln =LaIII, CeIII, SmIII and GdIII). The ligand and complexes were characterized by 1H, 13CNMR, elemental analysis (CHNO), FT-IR spectroscopy, GC-mass, Magnetic susceptibility Molar Conductivity and Thermo gravimetric analysis (TGA). Investigation of complexes suggest that two ligand molecules behaves as tridentate and the third one as bidentate as it present in zwitter ionic form with an additional one chloride ion to complete nine coordination geometry.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
Publisher: Scientia Research Library
Keywords: Salicylaldimine; Schiff base; Mononuclear complexes; Lanthanides
Depositing User: Nurul Ainie Mokhtar
Date Deposited: 30 Dec 2015 11:29
Last Modified: 30 Dec 2015 11:29
URI: http://psasir.upm.edu.my/id/eprint/35156
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