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Sorption removal of arsenic (V) by Sn-loaded poly(hydroxamic) acid chelating resin


Haron, Md. Jelas and Wan Yunus, Wan Md. Zin and Tan, W. C. and Kassim, Anuar (2007) Sorption removal of arsenic (V) by Sn-loaded poly(hydroxamic) acid chelating resin. Journal of Ion Exchange, 18 (4). pp. 240-245. ISSN 0915-860X; ESSN: 1884-3360


Sorption conditions of arsenate ions onto Sn-loaded poly (hydroxamic acid) chelating resin (Sn-PHA) have been studied. Sorption isotherms data correlated well to the Langmuir model with maximum capacity of 38.46 mg g-1 at pH 2. Sorption process follows pseudo-second order kinetics. Intraparticle diffusion was found to take part in sorption processes. The free energy (E) was 11.18 kJ mol-1 which shows the sorption is an ion-exchange process. Thermodynamic parameters, ΔH°, ΔS° and ΔG° were also calculated from the experimental data. Standard heat of sorption was found to be endothermic and entropy change value was calculated to be positive. Negative ΔG° value indicates that the sorption process for the arsenic anions onto Sn-PHA is spontaneous.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.5182/jaie.18.240
Publisher: Japan Association of Ion Exchange
Keywords: Tin-poly(hydroxamic acid) resin; Arsenic removal
Depositing User: Nurul Ainie Mokhtar
Date Deposited: 19 Sep 2016 09:27
Last Modified: 19 Sep 2016 09:27
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.5182/jaie.18.240
URI: http://psasir.upm.edu.my/id/eprint/34646
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