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[1,5] and [1,2] acetyl shifts in Diels-Alder adducts of 2-acetyl-6-methyl-l,4-benzoquinone


Ahmad, Faujan and Bruce, J. Malcolm and Khalafy, Jabbar and Sabetian, Khojasteh (1981) [1,5] and [1,2] acetyl shifts in Diels-Alder adducts of 2-acetyl-6-methyl-l,4-benzoquinone. Journal of the Chemical Society, Chemical Communications, 4. pp. 169-171. ISSN 0022-4936


Treatment of the Diels-Alder adduct 4a-acetyl-4a, 5, 8, 8a-tetrahydro-3-methyl-I, 4 naphthoquinone with pyridine-methanol or acetic anhydride leads to a [I, 5J acetyl shift to the 3-position which can be followed by a [1,2J acetyl shift to the 2-position (adduct numbering).

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science and Environmental Studies
DOI Number: https://doi.org/10.1039/C39810000169
Publisher: The Royal Society of Chemistry
Keywords: Diels-Alder
Depositing User: Mohd Hafiz Che Mahasan
Date Deposited: 13 Apr 2015 02:54
Last Modified: 13 Apr 2015 02:54
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1039/C39810000169
URI: http://psasir.upm.edu.my/id/eprint/33816
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