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(Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate.


Citation

Low, May Lee and S. A. Ravoof, Thahira Begum and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne and Tiekink, Edward R. T. (2013) (Pyridin-4-yl)methyl N′-(3-phenylallylidene)hydrazinecarbodithio­ate. Acta Crystallographica Section E: Structure Reports Online, 69 (pt.2). pp. 167-168. ISSN 1600-5368

Abstract

In the title compound, C16H15N3S2, the central C2N2S2 residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol­ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra­molecular chains along [1-10] are stabilized by N—H(...)N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C—H(...)π(pyridine) inter­actions.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536812051537
Publisher: International Union of Crystallography
Keywords: Single-crystal X-ray study; Data-to-parameter ratio = 15.1; R factor = 0.042.
Depositing User: Umikalthom Abdullah
Date Deposited: 30 May 2014 03:15
Last Modified: 01 Oct 2015 08:33
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536812051537
URI: http://psasir.upm.edu.my/id/eprint/29999
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