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Dimethylsulphoxide Complexes of Vanadium(III)


Sirat, Kamaliah and W.Smith, Peter (1992) Dimethylsulphoxide Complexes of Vanadium(III). Pertanika, 15 (2). pp. 137-142.


Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively

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Additional Metadata

Item Type: Article
Divisions: Faculty of Environmental Studies
Keywords: dimethyIsuIpboxide complexes, vanadium(ill).
Depositing User: Nur Izzati Mohd Zaki
Date Deposited: 19 Nov 2009 07:00
Last Modified: 27 May 2013 07:04
URI: http://psasir.upm.edu.my/id/eprint/2939
Statistic Details: View Download Statistic

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