UPM Institutional Repository

Benzyl N-[1-(thio­phen-2-yl)ethyl­idene)]-hydrazinecarbodi­thioate


Citation

Chan, Eddy Mun Hoe and Crouse, Karen Anne and Tarafder, M. Tofazzal H. and Mohd Yamin, Bohari (2003) Benzyl N-[1-(thio­phen-2-yl)ethyl­idene)]-hydrazinecarbodi­thioate. Acta Crystallographica Section E: Structure Reports Online, 59 (5). pp. 628-629. ISSN 1600-5368

Abstract

In the title compound, C14H14N2S3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragments, respectively. In the crystal structure, the molecules are linked by N-H...S hydrogen bonds between the amino group and the thiono S atoms and are arranged as dimers parallel to ab face.


Download File

[img]
Preview
PDF (Abstract)
Benzyl N-[1-(thiophen-2-yl)ethylidene]-hydrazinecarbodithioate.pdf

Download (83kB) | Preview

Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536803007517
Publisher: International Union of Crystallography
Keywords: Benzyl fragments; Bond lengths; Dithiocarbazate system; Intramolecular interactions
Depositing User: Nur Farahin Ramli
Date Deposited: 24 Jul 2013 03:52
Last Modified: 15 Jan 2018 06:00
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536803007517
URI: http://psasir.upm.edu.my/id/eprint/25098
Statistic Details: View Download Statistic

Actions (login required)

View Item View Item