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Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride.


Crouse, Karen Anne and Kar , Teng Chew and Yamin, Bohari M. and Seik, Weng Ng and Tarafder, M.T.H. (2003) Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride. Acta Crystallographica Section E: Structure Reports Online, 59 (2). o148-o150. ISSN 1600-5368


The title compound, [C7H10N3S2]+·Cl-, exists as an ionic compound of a dithiocarbazate system, with a zwitterionic +H3NNCS- moiety and a protonated pyridine ring. The C-S thione bond distance of the zwitterionic moiety [1.708 (2) Å] is longer than the normal double bond and the C-N of the carbazate moiety has double-bond character. The crystal packing is stabilized by intramolecular hydrogen bonds, which form a two-dimensional network perpendicular to b.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S160053680300014X
Publisher: International Union of Crystallography
Keywords: 2-picolychloride hydrochloride; Dithiocarbamic acids; Dithiocarbazate compounds.
Depositing User: Nur Farahin Ramli
Date Deposited: 24 Jul 2013 03:45
Last Modified: 27 Nov 2015 02:29
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S160053680300014X
URI: http://psasir.upm.edu.my/id/eprint/25097
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