Citation
Kamaludin, Nurul Farahana and Baba, Ibrahim and Awang, Normah and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T.
(2012)
Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV).
Acta Crystallographica Section E: Structure Reports Online, E68 (1).
m79-m80.
ISSN 1600-5368
Abstract
The title compound, [Sn(C4H9)2(C9H10NS2)2], features a tetrahedrally coordinated SnIV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the SnIV atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H(...)S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C—H(...)π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1107/S160053681105392X |
| Publisher: | International Union of Crystallography |
| Keywords: | Single-crystal Xray study. |
| Depositing User: | Nur Farahin Ramli |
| Date Deposited: | 25 Jul 2013 01:35 |
| Last Modified: | 21 Sep 2015 00:09 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S160053681105392X |
| URI: | http://psasir.upm.edu.my/id/eprint/25080 |
| Statistic Details: | View Download Statistic |
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