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Paulus, Georgiana and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (E)-[({[(3-Methylphenyl)methyl]sulfanyl}-methanethioyl)amino](1-phenylpentylidene)amine. Acta Crystallographica Section E: Structure Reports Online, 67 (6). pp. 1370-1383. ISSN 1600-5368; ESSN:1600-5368


In the structure of the title compound, C20H24N2S2, the central CN2S2 atoms are planar (r.m.s. deviation = 0.0205 Å) but both benzene rings are twisted out of this plane forming dihedral angles of 23.03 (6) and 84.75 (4)° (tol­yl); the n-butyl group occupies a position normal to the plane [N—C—C—C torsion angle = −84.33 (16)°]. The conformation of the imine bond [1.2888 (18) Å] is E. The syn arrangement of the thione S and amino H atoms enables the formation of N—H(...)S hydrogen bonds between centrosymmetrically related mol­ecules. These lead to eight-membered {(...)HNC=S}2 synthons which are further stabilized by proximate C—H(...)S interactions. The resulting dimeric aggregates are connected into a supra­molecular chain along the c axis by C—H(...)π(tol­yl) inter­actions.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536811016965
Publisher: International Union of Crystallography
Keywords: Single-crystal X-ray study.
Depositing User: Nur Farahin Ramli
Date Deposited: 15 Aug 2013 08:58
Last Modified: 28 Oct 2015 07:29
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536811016965
URI: http://psasir.upm.edu.my/id/eprint/24957
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