Citation
How, Fiona N.-F. and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim
(2007)
2-Naphthylmethyl N-(3-pyridylmethylene) hydrazinecarbodithioate.
Acta Crystallographica Section E: Structure Reports Online, 63 (7).
pp. 3133-3134.
ISSN 1600-5368; ESSN:1600-5368
Abstract
The title molecule, C18H15N3S2, is a trans-cis conformer. The thione S atom is in a trans configuration with respect to the pyridine ring but adopts a cis configuration with respect to the napthylmethyl substituent. In the crystal structure, molecules are linked by intermolecular N-H...N hydrogen bonds via[alpha]-N donor atoms and pyridyl N acceptor atoms into one-dimensional chains along the a axis. In addition, pairs of inversion-related dithiocarbazate groups and the attached pyridine groups are arranged with an interplanar distance 3.30 Å, leading to [pi]-[pi] stacking interactions. The crystal used for the structure determination was twinned.
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1107/S1600536807025676 |
| Publisher: | International Union of Crystallography |
| Keywords: | Dithiocarbazate; Naphthyl; Hydrazinecarbodithioate. |
| Depositing User: | Nur Farahin Ramli |
| Date Deposited: | 15 Aug 2013 07:41 |
| Last Modified: | 17 Sep 2015 03:35 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536807025676 |
| URI: | http://psasir.upm.edu.my/id/eprint/24955 |
| Statistic Details: | View Download Statistic |
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