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2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.


Citation

How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, E63 (7). pp. 3135-3136. ISSN 1600-5368; ESSN:1600-5368

Abstract

The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts a cis position with respect to the naphthalene ring across the C-S bond. There is a [pi]-[pi] stacking interaction between the naphthalene rings, with a centroid-centroid distance of 3.397 (2) Å.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536807025652
Publisher: International Union of Crystallography
Keywords: Schiff base.
Depositing User: Nur Farahin Ramli
Date Deposited: 19 Aug 2013 00:38
Last Modified: 17 Sep 2015 03:26
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536807025652
URI: http://psasir.upm.edu.my/id/eprint/24954
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