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Modification of montmorillonite by Difattyacyl thiourea using cation exchange process.


Citation

Hoidy , Wisam and Ahmad @ Ayob, Mansor and Al Mulla, Emad A. Jaffar and Ibrahim, Nor Azowa (2010) Modification of montmorillonite by Difattyacyl thiourea using cation exchange process. Oriental Journal of Chemistry, 26 (2). pp. 409-414. ISSN 0970-020X

Abstract

Cation exchange process was used to modify for montmorillonite (Na-MMT) by difatty acyl thiourea (DFAT). Basal spacing functional groups identification and thermal stability of this organomontmorillonite (OMMT) were characterized using X-ray Diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy arid thermogravimetric analysis (TGA) respectively. Elemental analysis was also used to know the composition of OMMT.The (XRD) results showed that the basal spacing of the treated clay with DFAT increased from 1.23 nm to 3.05 nm. The highest d-spacing was observed at 2.00 CEC. FTIR spectra illustrate that DFAT compound was successfully intercalated into the clay layers. Thermogravimetric analysis shows that the thermal decomposition of organoclay occurs with higher temperature than pure DFAT.


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Official URL or Download Paper: http://orientjchem.org/

Additional Metadata

Item Type: Article
Divisions: Faculty of Science
Publisher: Oriental Scientific Publishing Co.
Keywords: Sodium montmorillonite; Difatty acyl thiourea; Cation exchange process; Surfactant.
Depositing User: Nur Farahin Ramli
Date Deposited: 28 Aug 2013 01:37
Last Modified: 14 Sep 2015 08:28
URI: http://psasir.upm.edu.my/id/eprint/24840
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