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(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)


Citation

Abdul Muthalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Seik, Weng Ng and Tiekink, Edward R. T. (2010) (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (1087). pp. 1-12. ISSN 1600-5368

Abstract / Synopsis

The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supra­molecular arrays that stack along the b axis.


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Additional Metadata

Item Type: Article
Subject: crystal
Divisions: Faculty of Science
Publisher: International Union of Crystallography
Keywords: single-crystal X-ray
Depositing User: Najwani Amir Sariffudin
Date Deposited: 27 Oct 2011 08:41
Last Modified: 03 Nov 2015 01:07
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536810031636
URI: http://psasir.upm.edu.my/id/eprint/12627
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