Citation
Abdul Muthalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Seik, Weng Ng and Tiekink, Edward R. T.
(2010)
(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV).
Acta Crystallographica Section E: Structure Reports Online, 66 (1087).
pp. 1-12.
ISSN 1600-5368
Abstract
The SnIV atom in the title organotin dithiocarbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supramolecular arrays that stack along the b axis.
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Official URL or Download Paper: http://dx.doi.org/10.1107/S1600536810031636
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Additional Metadata
| Item Type: | Article |
|---|---|
| Subject: | crystal |
| Divisions: | Faculty of Science |
| Publisher: | International Union of Crystallography |
| Keywords: | single-crystal X-ray |
| Depositing User: | Najwani Amir Sariffudin |
| Date Deposited: | 27 Oct 2011 08:41 |
| Last Modified: | 03 Nov 2015 01:07 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536810031636 |
| URI: | http://psasir.upm.edu.my/id/eprint/12627 |
| Statistic Details: | View Download Statistic |
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