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Synergistic enhancement of jatropha methyl ester combustion via Fe2O3–SiO2 hybrid nano-additives and staged hydrogen enrichment in CI engines


Citation

Munimathan, Arunkumar and Senthil Kumar, K. and Vasanthi, R. and Alam, Mohammad Mukhtar and Hussain, Fayaz and Keçebaş, Ali (2026) Synergistic enhancement of jatropha methyl ester combustion via Fe2O3–SiO2 hybrid nano-additives and staged hydrogen enrichment in CI engines. International Journal of Hydrogen Energy, 231. art. no. 154857. pp. 1-22. ISSN 0360-3199

Abstract

This study investigates a dual-fuel enhancement strategy that integrates Fe2O3–SiO2 hybrid nano-additives with staged hydrogen enrichment to overcome the combustion inefficiencies and emission drawbacks commonly observed in Jatropha Methyl Ester (JME) biodiesel. While previous studies have generally examined either hydrogen enrichment or nanoparticle additiona isolated interventions, this research uniquely evaluates their combined effects under systematically controlled engine operating conditions. Experiments were conducted on a single-cylinder, direct-injection (DI) diesel engine using six fuel configurations, ranging from neat diesel to B20 blends containing 50 ppm Fe2O3–SiO2 and hydrogen injection rates of 2-6 L/min, tested across five discrete load levels. The results demonstrate that the combined nano-additive and hydrogen-enriched fuel promoted enhanced premixed combustion, accelerated flame propagation, and shortened ignition delay, resulting in a peak brake thermal efficiency (BTE) 32.5%, a 15.2% increase over diesel. The optimized blend (B20N50H4) had a 24.7% thru cut in brake-specific fuel consumption (BSFC) and comparable NOx emissions as diesel, with the success of an approximate 24% reduction in smoke amplification. There were also better emission profiles, as the emissions were 24% lighter than that of conventional diesel, which highlights the catalytic quality of the hybrid nanoparticles and the clean-burning nature of hydrogen. These indicate that the combined approach of hydrogen-enrichment and nanoadditive allows clean and more efficient combustion of bio-diesel without the engine architecture requirements. In line with this, this solution is an acceptable avenue to development and implementation of low-carbon dual-fuel technologies.


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Additional Metadata

Item Type: Article
Subject: Renewable Energy, Sustainability and the Environment
Subject: Fuel Technology
Subject: Condensed Matter Physics
Divisions: Faculty of Engineering
DOI Number: https://doi.org/10.1016/j.ijhydene.2026.154857
Publisher: Elsevier Ltd
Keywords: Dual-fuel enhancement; Emission reduction; Engine performance; Fe2o3–sio2hybrid nano-additives; Hydrogen-enriched biodiesel combustion; Jatropha methyl ester biodiesel
Sustainable Development Goals (SDGs): SDG 7: Affordable and Clean Energy, SDG 13: Climate Action, SDG 9: Industry, Innovation and Infrastructure
Depositing User: Ms. Siti Radziah Mohamed@mahmod
Date Deposited: 23 Jun 2026 01:15
Last Modified: 23 Jun 2026 01:15
Altmetrics: https://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1016/j.ijhydene.2026.154857
URI: http://psasir.upm.edu.my/id/eprint/124681
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