Mechanosynthesis and mechanochemical treatment of bismuthdoped vanadium phosphorus oxide catalysts for the partial oxidation of n-butane to maleic anhydride

Yap, Taufiq Yun Hin and Wong, Y. C. and Kamiya, Y. and Tang, W. J. (2008) Mechanosynthesis and mechanochemical treatment of bismuthdoped vanadium phosphorus oxide catalysts for the partial oxidation of n-butane to maleic anhydride. Journal of Natural Gas Chemistry, 17 (3). pp. 232-237. ISSN 1003-9953

Full text not available from this repository.

Official URL: http://dx.doi.org/10.1016/S1003-9953(08)60056-0

Abstract

Three Bi-doped vanadyl pyrophosphate catalysts were prepared via dihydrate route (VPD method), which consisted of different preparation methods including mechanosynthesis, mechanochemical treatment, and the conventional reflux method. The catalysts produced by the above three methods were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), and temperature programmed reduction (TPR). Catalytic evaluation for the partial oxidation of n-butane to maleic anhydride (MA) was also carried out. The XRD patterns of all the Bi-doped catalysts showed the main peaks of pyrophosphate phase. Lower intensity peaks were observed for the mechanochemically treated Bi-doped catalyst (VPDBiMill) with two additional small peaks corresponding to the presence of a small amount of V5+ phase. The TPR profiles showed that the highest amount of active oxygen species, i.e, V4+–O− pair, responsible for n-butane activation, was removed from VPDBiMill. Furthermore, from the catalytic test results, the graph of selectivity to MA as a function of the conversion of n-butane demonstrated that VPDBiMill was the most selective catalyst. This suggests that the mechanochemical treatment of vanadium phosphate catalyst (VPDBiMill) is a potential method to improve the catalytic properties for the partial oxidation of n-butane to maleic anhydride.

Item Type:Article
Keyword:mechanosynthesis, mechanochemical treatment, bismuth,vanadyl pyrophosphate
Faculty or Institute:Faculty of Science
Publisher:Elsevier
Altmetrics:http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1016/S1003-9953(08)60056-0
ID Code:6212
Deposited By: Najwani Amir Sariffudin
Deposited On:12 May 2010 06:52
Last Modified:06 Jun 2011 04:38

Repository Staff Only: Edit item detail


Universiti Putra Malaysia Institutional Repository

Universiti Putra Malaysia Institutional Repository is an on-line digital archive that serves as a central collection and storage of scientific information and research at the Universiti Putra Malaysia.

Currently, the collections deposited in the IR consists of Master and PhD theses, Master and PhD Project Report, Journal Articles, Journal Bulletins, Conference Papers, UPM News, Newspaper Cuttings, Patents and Inaugural Lectures.

As the policy of the university does not permit users to view thesis in full text, access is only given to the first 24 pages only.