Sirat, Kamaliah and W.Smith, Peter (1992) Dimethylsulphoxide Complexes of Vanadium(III). Pertanika, 15 (2). pp. 137-142.
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Abstract
Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively
| Item Type: | Article |
|---|---|
| Keyword: | dimethyIsuIpboxide complexes, vanadium(ill). |
| Faculty or Institute: | Faculty of Environmental Studies |
| ID Code: | 2939 |
| Deposited By: | Nur Izzati Mohd Zaki |
| Deposited On: | 19 Nov 2009 15:00 |
| Last Modified: | 19 Nov 2009 15:00 |
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