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Dimethylsulphoxide Complexes of Vanadium(III)

Sirat, Kamaliah and W.Smith, Peter (1992) Dimethylsulphoxide Complexes of Vanadium(III). Pertanika, 15 (2). pp. 137-142.

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Abstract

Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively

Item Type:Article
Keyword:dimethyIsuIpboxide complexes, vanadium(ill).
Faculty or Institute:Faculty of Environmental Studies
ID Code:2939
Deposited By: Nur Izzati Mohd Zaki
Deposited On:19 Nov 2009 15:00
Last Modified:27 May 2013 15:04

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