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Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation


Citation

Abdollahi, Yadollah and Abdullah, Abdul Halim and Zainal, Zulkarnain and Yusof, Nor Azah (2012) Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation. International Journal of Molecular Sciences, 13 (1). pp. 302-315. ISSN 1422-0067; ESSN:1422-0067

Abstract / Synopsis

Photocatalytic degradation of p-cresol was carried out using ZnO under UV irradiation. The amount of photocatalyst, concentration of p-cresol and pH were studied as variables. The residual concentration and mineralization of p-cresol was monitored using a UV-visible spectrophotometer and total organic carbon (TOC) analyzer, respectively. The intermediates were detected by ultra high pressure liquid chromatography (UPLC). The highest photodegradation of p-cresol was observed at 2.5 g/L of ZnO and 100 ppm of pcresol. P-cresol photocatalytic degradation was favorable in the pH range of 6-9. The detected intermediates were 4-hydroxy-benzaldehyde and 4-methyl-1,2-benzodiol. TOC studies show that 93% of total organic carbon was removed from solution during irradiation time. Reusability shows no significant reduction in photocatalytic performance in photodegrading p-cresol.


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: 10.3390/ijms13010302
Publisher: MDPI
Keywords: Photocatalytic degradation; P-cresol; Mineralizatin; ZnO; UV
Depositing User: Nur Farahin Ramli
Date Deposited: 12 Jul 2013 16:21
Last Modified: 10 Feb 2016 16:08
URI: http://psasir.upm.edu.my/id/eprint/25222
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