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Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri.


Citation

Ee, Gwendoline Cheng Lian and Siau, Hui Mah and Huey, Chong Kwong and Soek, Sin Teh and Mohamed Tahir, Mohamed Ibrahim and Silong, Sidik (2011) Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri. Acta Crystallographica Section E: Structure Reports Online, 67 (10). pp. 2607-2608. ISSN 1600-5368; ESSN:1600-5368

Abstract

The title compound [systematic name: 5,10-di­hy­droxy-2,2-di­methyl-12-(2-methyl­but-3-en-2-yl)­pyrano[3,2-b]xanthen-6(2H)-one], C23H22O5, isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methyl­but-3-en-2-yl side chain. The tricyclic xanthone ring system is almost planar [maximum deviation = 0.093 (2) Å], whereas the pyran­oid ring is in a distorted boat conformation. The 2-methyl­but-3-en-2-yl side chain is in a synperiplanar conformation. There are two intra­molecular O—H(...)O hydrogen bonds. In the crystal, mol­ecules are linked by C—H(...)O inter­actions, forming a zigzag chain propagating in [010].


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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: https://doi.org/10.1107/S1600536811036294
Publisher: International Union of Crystallography
Keywords: Caloxanthone C; Pyranoxanthone; Calophyllum soulattri.
Depositing User: Nur Farahin Ramli
Date Deposited: 19 Aug 2013 03:07
Last Modified: 09 Sep 2015 03:19
Altmetrics: http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536811036294
URI: http://psasir.upm.edu.my/id/eprint/24933
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