(2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).

Citation

Jamaluddin, Nur Amirah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II). Acta Crystallographica Section E: Structure Reports Online, 67. pp. 384-385. ISSN 1600-5368

Abstract

The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C-H...S interactions and these are connected into layers that stack along the c axis via [pi]-[pi] interactions [Cg(pyridyl)...Cg(pyridyl) = 3.6587 (13) Å].

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Additional Metadata

Item Type:	Article
Divisions:	Faculty of Science
DOI Number:	https://doi.org/10.1107/S1600536811006878
Publisher:	International Union of Crystallography
Keywords:	Crystal; Atom; Binaphthalene; Chloroform.
Depositing User:	Nur Farahin Ramli
Date Deposited:	28 Feb 2014 07:58
Last Modified:	06 Oct 2015 04:07
Altmetrics:	http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S1600536811006878
URI:	http://psasir.upm.edu.my/id/eprint/24787
Statistic Details:	View Download Statistic

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