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Abdul Mutalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) (N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV). Acta Crystallographica Section E: Structure Reports Online, 67. pp. 372-373. ISSN 1600-5368

Abstract / Synopsis

The SnIV atom in the title diorganotin dithiocarbamate, [Sn(C4H9)2Cl(C10H12NS2)], is pentacoordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two C atoms of the Sn-bound tert-butyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square pyramidal and trigonal bipyramidal with a slight tendency towards the former. In the crystal structure, C-H...[pi] contacts link centrosymmetrically related molecules into dimeric aggregates.

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Additional Metadata

Item Type: Article
Divisions: Faculty of Science
DOI Number: 10.1107/S1600536811006398
Publisher: International Union of Crystallography
Keywords: SnIV atom; Diorganotin dithiocarbamate; Compound.
Depositing User: Nur Farahin Ramli
Date Deposited: 28 Feb 2014 16:12
Last Modified: 16 Oct 2015 15:07
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