Keyword Search:

Differential pulse polarography and voltammetry with an automated microprocessor-based polarograph and a static mercury drop electrode

Tan, W. T. and Tan, G. S. (1985) Differential pulse polarography and voltammetry with an automated microprocessor-based polarograph and a static mercury drop electrode. Pertanika, 8 (3). pp. 399-409. ISSN 0126-6128

[img] PDF
5Mb

Abstract

Differential pulse polarography using an automated, microprocessor- based polarographic analyzer equipped with a static mercury drop electrode has been evaluated with respect to pulse amplitude, scan rate, drop time (t), and drop area. Variation of peak current, z"p' with drop area and t - Y2, with some pulse amplitudes agree reasonably well with theory. However, dependence of and E or i scan rate and on pulse amplitude at very large and very small amplitudes was found to devide fron i theory. Similar trends were also found for anodic stripping voltammetry when differential pulse stripping was used. The precision attainable by both techniques was good. Copper peaks demonstrated good precision only when copper was plated out individually during anodic stripping voltammetry.

Item Type:Article
Keyword:Analytical evaluation; Pulse; Stripping; Precision
Faculty or Institute:Faculty of Environmental Studies
Publisher:Universiti Pertanian Malaysia
ID Code:2323
Deposited By: Nur Izzati Mohd Zaki
Deposited On:12 Nov 2009 14:43
Last Modified:09 Mar 2015 14:27

Repository Staff Only: Edit item detail