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Abdul Muthalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Seik, Weng Ng and Tiekink, Edward R. T. (2010) (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (1087). pp. 1-12. ISSN 1600-5368

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The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supra­molecular arrays that stack along the b axis.

Item Type:Article
Keyword:single-crystal X-ray
Faculty or Institute:Faculty of Science
Publisher:International Union of Crystallography
ID Code:12627
Deposited By: Najwani Amir Sariffudin
Deposited On:27 Oct 2011 16:41
Last Modified:03 Nov 2015 09:07

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