Abdul Muthalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Seik, Weng Ng and Tiekink, Edward R. T. (2010) (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (1087). pp. 1-12. ISSN 1600-5368
Official URL: http://dx.doi.org/10.1107/S1600536810031636
The SnIV atom in the title organotin dithiocarbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supramolecular arrays that stack along the b axis.
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