Citation
Alzaalouk, Amna Salem and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Ng, Seik Weng and Tiekink, Edward Richard Tom
(2010)
Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II).
Acta Crystallographica Section E: Structure Reports Online, 66 (pt. 9).
m1165-m1166.
ISSN 1600-5368
Abstract
Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).
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Official URL or Download Paper: http://scripts.iucr.org/cgi-bin/paper?bt5329
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Additional Metadata
| Item Type: | Article |
|---|---|
| Divisions: | Faculty of Science |
| DOI Number: | https://doi.org/10.1107/S160053681003367 |
| Publisher: | International Union of Crystallography |
| Keywords: | Single-crystal X-ray |
| Depositing User: | Nurul Ainie Mokhtar |
| Date Deposited: | 08 Jun 2015 06:14 |
| Last Modified: | 22 Oct 2015 06:29 |
| Altmetrics: | http://www.altmetric.com/details.php?domain=psasir.upm.edu.my&doi=10.1107/S160053681003367 |
| URI: | http://psasir.upm.edu.my/id/eprint/13428 |
| Statistic Details: | View Download Statistic |
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